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SPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THE INVESTIGATION OF ELECTRODE-REACTION MECHANISMS

Abstract:

Spectrofluorimetric hydrodynamic voltammetry (SFV) is used to study the electroreduction of crystal violet in acetonitrile solution. The SFV technique is shown to have high sensitivity and to complement conventional electrochemical experiments through its identification of leucocrystal violet as an electrolysis product generated in low concentration in addition to the radical species formed as a one-electron adduct of the parent compound and previously thought to be produced exclusively. Mech...

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Publication status:
Published

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Publisher copy:
10.1021/j100052a045

Authors


COMPTON, R More by this author
WELLINGTON, R More by this author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY
Volume:
98
Issue:
1
Pages:
270-273
Publication date:
1994-01-06
DOI:
EISSN:
1541-5740
ISSN:
0022-3654
URN:
uuid:77668ca6-ff76-421c-97b4-915787f8d9f9
Source identifiers:
44353
Local pid:
pubs:44353
Language:
English

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