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Channel electrode voltammetry: the kinetics of the complexation of the chloranil radical anion with M2+ ions by waveshape analysis

Abstract:

Channel electrode waveshape analysis is employed to determine the rate of complexation of the radical anion of chloranil, with Mg2+ or Ba2+ ions in acetonitrile solution. The presence of less than stoichiometric amounts of M2+ results in a voltammetric wave for the reduction of chloranil which is split into two regions. At less negative potentials, the Nernstian equilibrium of chloranil and its radical anion is perturbed by the following reaction, resulting in current flowing at a more positi...

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Authors


Cooper, JA More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Okazaki, S More by this author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
442
Issue:
1-2
Pages:
201-206
Publication date:
1998-01-30
DOI:
ISSN:
0022-0728
URN:
uuid:775b61cd-d87a-4fea-afe8-9609ffb11cd3
Source identifiers:
36389
Local pid:
pubs:36389
Language:
English
Keywords:

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