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Conformational studies of oligomeric oxetane-based dipeptide isosteres derived from L-rhamnose or D-xylose.

Abstract:

Conformational investigations have been undertaken on oligomers (dimers, tetramers, hexamers) of five closely related oxetane-based dipeptide isosteres. All the oligomers were subjected to a range of studies by NMR, FT-IR and CD spectroscopy. The oligomers derived from methyl 2,4-anhydro-5-azido-3-O-tert-butyldimethylsilyl-5-deoxy-L-rhamnonate 'monomer' all exhibited evidence of ordered conformations in chloroform and 2,2,2-trifluoroethanol (TFE) solution. 5-Acetamido and N-methylamide deriva...

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Publication status:
Published

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Publisher copy:
10.1002/psc.658

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Journal:
Journal of peptide science : an official publication of the European Peptide Society
Volume:
11
Issue:
9
Pages:
517-524
Publication date:
2005-09-05
DOI:
EISSN:
1099-1387
ISSN:
1075-2617
URN:
uuid:773a2c5a-5be7-4f24-b359-983d774b8e2a
Source identifiers:
39654
Local pid:
pubs:39654

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