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Cyclic and open-chain aza-oxa ferrocene-functionalised derivatives as receptors for the selective electrochemical sensing of toxic heavy metal ions in aqueous environments

Abstract:

A new family of aza-oxa open-chain and macrocyclic molecules functionalised with ferrocenyl groups have been synthesized and characterised. The crystal structures of the [HL1][PF6], [H2L3][PF6]2, [H2L4][PF6]2 and [H2L5][PF6]2 salts have been determined by single crystal X-ray procedures {L1 = 10-ferrocenylmethyl- 1,4,7-trioxa-10-azacyclododecane, L3 = 7,13-bis(ferrocenyl)-1,4,10-trioxa-7,13-diazacyclopentadecane, L4 = 1,8-bis[bis(ferrocenylmethylamino)]-3,6-dioxaoctane, L5 = 1,8-bis(ferroceny...

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Publication status:
Published

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Publisher copy:
10.1039/a902008j

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
14
Pages:
2359-2369
Publication date:
1999-01-01
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:75845293-b49d-4ffb-b1b5-a740e9e2f7c4
Source identifiers:
37028
Local pid:
pubs:37028
Language:
English

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