- Abstract:
-
Tetramethylammonium copper(I) zinc(II) cyanide, which consists of N(CH(3))(4)(+) ions trapped within a cristobalite-like metal cyanide framework, has been studied by variable-temperature powder and single-crystal X-ray diffraction. Its coefficient of thermal expansion is approximately zero over the temperature range 200-400 K and comparable with the best commercial zero thermal expansion materials. The atomic displacement parameters, apparent bond lengths, and structure of a low-temperature, ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ja906895j
-
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- Journal:
- Journal of the American Chemical Society
- Volume:
- 132
- Issue:
- 1
- Pages:
- 10-11
- Publication date:
- 2010-01-05
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- URN:
-
uuid:7543df45-0ecf-4db5-9807-fefdb5156f46
- Source identifiers:
-
50529
- Local pid:
- pubs:50529
- Language:
- English
- Copyright date:
- 2010
Journal article
Zero thermal expansion in a flexible, stable framework: tetramethylammonium copper(I) zinc(II) cyanide.
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