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Zero thermal expansion in a flexible, stable framework: tetramethylammonium copper(I) zinc(II) cyanide.

Abstract:

Tetramethylammonium copper(I) zinc(II) cyanide, which consists of N(CH(3))(4)(+) ions trapped within a cristobalite-like metal cyanide framework, has been studied by variable-temperature powder and single-crystal X-ray diffraction. Its coefficient of thermal expansion is approximately zero over the temperature range 200-400 K and comparable with the best commercial zero thermal expansion materials. The atomic displacement parameters, apparent bond lengths, and structure of a low-temperature, ...

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Publication status:
Published

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Publisher copy:
10.1021/ja906895j

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Journal:
Journal of the American Chemical Society
Volume:
132
Issue:
1
Pages:
10-11
Publication date:
2010-01-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:7543df45-0ecf-4db5-9807-fefdb5156f46
Source identifiers:
50529
Local pid:
pubs:50529
Language:
English

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