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NOVEL MONO-FERROCENYL AND DI-FERROCENYL BIPYRIDYL LIGANDS - SYNTHESES, ELECTROCHEMISTRY, AND ELECTROPOLYMERIZATION STUDIES OF THEIR RUTHENIUM(II) COMPLEXES

Abstract:
The syntheses and electrochemical properties of new mono- and di-ferrocenyl bipyridyl ligands containing trans conjugated olefinic linkages between the ferrocene redox centres and the 4,4′-substituted 2,2′-bipyridine (bipy) moieties are described. The corresponding ruthenium(II) complexes have been prepared and one complex, [RuL4(bipy)2][PF6]2[L4 = 4,4′-bis(ferrocenylvinyl)-2,2′-bipyridine], undergoes electrochemical polymerisation to produce an electrochromic polymer film.
Publication status:
Published

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Publisher copy:
10.1039/dt9900003283

Authors


MORTIMER, R More by this author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
11
Pages:
3283-3288
Publication date:
1990-11-05
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:739e3253-4428-4820-b64b-53807b957c42
Source identifiers:
46079
Local pid:
pubs:46079
Language:
English

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