- Abstract:
- A catalyst generated from Pd(OAc)2 and dppp is effective for the direct intramolecular arylation of alkenyl triflates. Conjugated alkene-arene-containing carbocycles are produced in good yield. The process tolerates a variety of aryl substituents as well a simple heteroaryl groups. Electron-deficient aryl rings deliver faster reactions.
- Publication status:
- Published
- Publisher copy:
- 10.1021/ol702044z
-
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- Journal:
- Organic letters
- Volume:
- 9
- Issue:
- 21
- Pages:
- 4391-4393
- Publication date:
- 2007-10-05
- DOI:
- EISSN:
-
1523-7052
- ISSN:
-
1523-7060
- URN:
-
uuid:739b1149-bd0f-4b72-9557-ad4820d44177
- Source identifiers:
-
52472
- Local pid:
- pubs:52472
- Language:
- English
- Keywords:
- Copyright date:
- 2007
Journal article
Intramolecular palladium-catalyzed direct arylation of alkenyl triflates.
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