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Lanthanide complexes of DOTA monoamide derivatives bearing an isophthalate pendent arm.

Abstract:
An isophthalate-bearing DOTA monoamide derivative has been synthesised and used to prepare a family of lanthanide complexes. Luminescence and NMR studies in solution show that the predominant form of the complexes in solution is a mono-capped square antiprism about the lanthanide centre, in which a solvent molecule occupies the ninth coordination site. The crystal structure of the terbium complex is presented and is in close agreement with the solution state data.
Publication status:
Published

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Publisher copy:
10.1039/c1dt11029b

Authors


Shiells, EJ More by this author
Natrajan, LS More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
40
Issue:
43
Pages:
11451-11457
Publication date:
2011-11-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:735db92d-ca52-4cdc-b5f1-e9dfbe9173cc
Source identifiers:
180779
Local pid:
pubs:180779

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