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NEW EXPERIMENTAL-METHOD FOR STUDYING ROTATIONALLY STATE-SELECTED ION-MOLECULE REACTIONS

Abstract:

A new apparatus is described in which a beam of molecular ions in a selected vibration-rotation state is prepared by field ionization of high Rydberg states, in an adaptation of the zero-kinetic-energy photoelectron technique. The state-selected ions undergo low energy reactive collisions within a molecular beam and the ionic products are detected in a quadrupole mass filter. The Rydberg states are populated by two-color stepwise multiphoton excitation, and by tuning to the pseudocontinuum of...

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Publication status:
Published

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Publisher copy:
10.1063/1.467875

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
101
Issue:
12
Pages:
10609-10617
Publication date:
1994-12-15
DOI:
ISSN:
0021-9606
URN:
uuid:73243e7b-5405-4e27-a8da-234f78c7d943
Source identifiers:
44617
Local pid:
pubs:44617

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