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Thallium pi-cation complexation by calix[4]tubes: (205)Tl NMR and x-ray evidence.

Abstract:

Thallium cation complexation by calix[4]tubes has been investigated by a combination of (205)Tl, (1)H NMR and ES MS demonstrating the solution formation of a dithallium complex in which the cations are held in the calix[4]arene cavities. In addition, the structure of the complex has been determined in the solid state revealing the cations to be held exclusively by pi-cation interactions. Furthermore, this crystal structure has been used as the basis for molecular dynamics simulations to confi...

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Publication status:
Published

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Publisher copy:
10.1021/ic025884x

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
42
Issue:
3
Pages:
729-734
Publication date:
2003-02-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:71fd276f-5fe7-4e10-9292-5b688e8ad28b
Source identifiers:
32306
Local pid:
pubs:32306
Language:
English

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