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Synthesis and reactivity of rare-earth metal phosphaethynolates

Abstract:

Over the course of the last six years, research on the synthesis and reactivity of molecular metal phosphaketenes (M–PCO) has gained increasing attention. However, lanthanide complexes of the heavier group 15 cyanate analogue PCO− have not been investigated so far. Herein we present exemplar studies on the nature and reactivity of rare-earth phosphaethynolato-complexes using three characteristic representatives of the rare-earth metals: Y, Nd and Sm. Our investigations comprise both +2 and +3...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c8dt03427c

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
ORCID:
0000-0002-3462-6197
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Lady Margaret Hall
Role:
Author
ORCID:
0000-0002-7311-1663
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Dalton Transactions Journal website
Volume:
47
Issue:
37
Pages:
13016-13024
Publication date:
2018-08-23
Acceptance date:
2018-08-22
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Pmid:
30156233
Source identifiers:
911974
Language:
English
Pubs id:
pubs:911974
UUID:
uuid:71a0c07d-ee76-4c42-b555-0737a5bb947e
Local pid:
pubs:911974
Deposit date:
2019-02-18

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