Journal article
Synthesis and reactivity of rare-earth metal phosphaethynolates
- Abstract:
-
Over the course of the last six years, research on the synthesis and reactivity of molecular metal phosphaketenes (M–PCO) has gained increasing attention. However, lanthanide complexes of the heavier group 15 cyanate analogue PCO− have not been investigated so far. Herein we present exemplar studies on the nature and reactivity of rare-earth phosphaethynolato-complexes using three characteristic representatives of the rare-earth metals: Y, Nd and Sm. Our investigations comprise both +2 and +3...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
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(Accepted manuscript, pdf, 1.4MB)
-
- Publisher copy:
- 10.1039/c8dt03427c
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Authors
Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Dalton Transactions Journal website
- Volume:
- 47
- Issue:
- 37
- Pages:
- 13016-13024
- Publication date:
- 2018-08-23
- Acceptance date:
- 2018-08-22
- DOI:
- EISSN:
-
1477-9234
- ISSN:
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1477-9226
- Pmid:
-
30156233
- Source identifiers:
-
911974
Item Description
- Language:
- English
- Pubs id:
-
pubs:911974
- UUID:
-
uuid:71a0c07d-ee76-4c42-b555-0737a5bb947e
- Local pid:
- pubs:911974
- Deposit date:
- 2019-02-18
Terms of use
- Copyright holder:
- Bestgen et al
- Copyright date:
- 2018
- Notes:
- © 2018 Bestgen et al. This is the accepted manuscript version of the article. The final version is available online from the Royal Society of Chemistry at: https://doi.org/10.1039/C8DT03427C
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