Journal article
PHOTOELECTROCHEMICAL REDUCTION OF P-HALONITROBENZENES
- Abstract:
-
A detailed and comparative mechanistic study of the photoelectrochemical dehalogenation of the four p-halonitrobenzenes, X-C6H 4-NO2 (X = F, Cl, Br, or I) in acetonitrile solution is reported. In the case of p-iodonitrobenzene, iodide loss is accomplished by electrochemical reduction alone. The formation of l- is shown to take place via an ECE process with the ultimate generation of the radical anion of nitrobenzene. Dual photo- and electro-chemical activation of p-chloronitrobenzene and p-br...
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- Publication status:
- Published
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- Publisher copy:
- 10.1039/p29940001581
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Authors
Bibliographic Details
- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
- Issue:
- 7
- Pages:
- 1581-1587
- Publication date:
- 1994-07-01
- DOI:
- EISSN:
-
1364-5471
- ISSN:
-
0300-9580
- Source identifiers:
-
44484
Item Description
- Language:
- English
- UUID:
-
uuid:707308c2-ff41-4b17-ac33-0d0af0c0b743
- Local pid:
- pubs:44484
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 1994
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