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PHOTOELECTROCHEMICAL REDUCTION OF P-HALONITROBENZENES

Abstract:

A detailed and comparative mechanistic study of the photoelectrochemical dehalogenation of the four p-halonitrobenzenes, X-C6H 4-NO2 (X = F, Cl, Br, or I) in acetonitrile solution is reported. In the case of p-iodonitrobenzene, iodide loss is accomplished by electrochemical reduction alone. The formation of l- is shown to take place via an ECE process with the ultimate generation of the radical anion of nitrobenzene. Dual photo- and electro-chemical activation of p-chloronitrobenzene and p-br...

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Publication status:
Published

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Publisher copy:
10.1039/p29940001581

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Issue:
7
Pages:
1581-1587
Publication date:
1994-07-05
DOI:
EISSN:
1364-5471
ISSN:
0300-9580
URN:
uuid:707308c2-ff41-4b17-ac33-0d0af0c0b743
Source identifiers:
44484
Local pid:
pubs:44484
Language:
English

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