Journal article icon

Journal article

Experimental Comparison of the Marcus-Hush and Butler-Volmer Descriptions of Electrode Kinetics. The One-Electron Oxidation of 9,10-Diphenylanthracene and One-Electron Reduction of 2-Nitropropane Studied at High-Speed Channel Microband Electrodes

Abstract:

We present an experimental comparative evaluation of the Marcus-Hush (MH) and Butler-Volmer (BV) kinetic formalisms. Numerical simulations using both kinetic models are used to fit experimental voltammetry of the one-electron oxidation of 9,10-diphenylanthracene (DPA) and the one-electron reduction of 2-nitropropane (NP) at a high-speed channel microband electrode. For DPA the Butler-Volmer and Marcus-Hush formalisms yield indistinguishable fits, as expected for a system with fast electrode k...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/jp2034246

Authors


Suwatchara, D More by this author
Henstridge, MC More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
115
Issue:
30
Pages:
14876-14882
Publication date:
2011-08-04
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:703fe5a2-2c26-47dc-b796-79ea663387b2
Source identifiers:
172494
Local pid:
pubs:172494
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP