The calculation of the Marcus free energy curves for electron transfer events between a redox species and a metallic electrode in an atomistic simulation designed to model the electrochemical interface with an ionic liquid is described. The calculation is performed on a system comprising a molten salt mixture confined between model metallic electrodes [Reed et al., J. Chem. Phys. 126, 084704 (2007)] which are maintained at a constant electrical potential. The calculation therefore includes a ...Expand abstract
- Publication status:
- Publisher copy:
- Copyright date:
Electrochemical charge transfer at a metallic electrode: a simulation study.
Views and Downloads
If you are the owner of this record, you can report an update to it here: Report update to this record