Journal article
Metal-Organic Nanosheets Formed via Defect-Mediated Transformation of a Hafnium Metal-Organic Framework
- Abstract:
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We report a hafnium-containing MOF, hcp UiO-67(Hf), which is a ligand-deficient layered analogue of the face-centered cubic fcu UiO-67(Hf). hcp UiO-67 accommodates its lower ligand:metal ratio compared to fcu UiO-67 through a new structural mechanism: the formation of a condensed "double cluster" (Hf12O8(OH)14), analogous to the condensation of coordination polyhedra in oxide frameworks. In oxide frameworks, variable stoichiometry can lead to more complex defect structures, e.g., crystallogra...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Version of record, pdf, 3.5MB)
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- Publisher copy:
- 10.1021/jacs.7b00106
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Authors
Funding
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 139
- Issue:
- 15
- Pages:
- 5397-5404
- Publication date:
- 2017-03-27
- Acceptance date:
- 2017-01-01
- DOI:
- EISSN:
-
1520-5126
- ISSN:
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0002-7863
- Source identifiers:
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688014
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:688014
- UUID:
-
uuid:6f35dc6f-43da-4979-a431-cff5052eb9cf
- Local pid:
- pubs:688014
- Deposit date:
- 2017-08-07
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2017
- Notes:
- © 2017 American Chemical Society. ACS AuthorChoice - This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
- Licence:
- CC Attribution (CC BY)
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