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Metal-Organic Nanosheets Formed via Defect-Mediated Transformation of a Hafnium Metal-Organic Framework

Abstract:

We report a hafnium-containing MOF, hcp UiO-67(Hf), which is a ligand-deficient layered analogue of the face-centered cubic fcu UiO-67(Hf). hcp UiO-67 accommodates its lower ligand:metal ratio compared to fcu UiO-67 through a new structural mechanism: the formation of a condensed "double cluster" (Hf12O8(OH)14), analogous to the condensation of coordination polyhedra in oxide frameworks. In oxide frameworks, variable stoichiometry can lead to more complex defect structures, e.g., crystallogra...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/jacs.7b00106

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Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
139
Issue:
15
Pages:
5397-5404
Publication date:
2017-03-27
Acceptance date:
2017-01-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Source identifiers:
688014
Language:
English
Keywords:
Pubs id:
pubs:688014
UUID:
uuid:6f35dc6f-43da-4979-a431-cff5052eb9cf
Local pid:
pubs:688014
Deposit date:
2017-08-07

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