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Journal article

Electrooxidation of the iodides [C(4)mim]I, LiI, NaI, KI, RbI, and CsI in the room temperature ionic liquid [C(4)mim][NTf2]

Abstract:: The electrochemical oxidation of l-butyl-3-methylimidazolium iodide, [C4mim]I, has been investigated by cyclic voltammetry at a platinum microelectrode at varying concentrations in the RTIL l-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [C4mim][NTf2]. Two oxidation peaks were observed. The first peak is assigned to the oxidation of iodide to triiodide, in an overall two-electron process: 3I- - 2e-→ I3-. At higher potentials, the electrogenerated triiodide oxidizes to iodine, i...
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Publication status:: Published

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APA Style

Rogers, E., Silvester, D., Aldous, L., Hardacre, C., & Compton, R. (2008). Electrooxidation of the iodides [C(4)mim]I, LiI, NaI, KI, RbI, and CsI in the room temperature ionic liquid [C(4)mim][NTf2]. JOURNAL OF PHYSICAL CHEMISTRY C, 112(16), 6551–6557.

MLA Style

Rogers, E., et al. “Electrooxidation of the Iodides [C(4)Mim]I, LiI, NaI, KI, RbI, and CsI in the Room Temperature Ionic Liquid [C(4)Mim][NTf2].” JOURNAL OF PHYSICAL CHEMISTRY C, vol. 112, no. 16, 2008, pp. 6551–57.

Chicago Style

Rogers, E, D Silvester, L Aldous, C Hardacre, and R Compton. 2008. “Electrooxidation of the Iodides [C(4)Mim]I, LiI, NaI, KI, RbI, and CsI in the Room Temperature Ionic Liquid [C(4)Mim][NTf2].” JOURNAL OF PHYSICAL CHEMISTRY C 112 (16): 6551–57.
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Publisher copy:: 10.1021/jp800145k

Authors

+ Rogers, E More by this author

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Author

+ Silvester, D More by this author

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Author

+ Aldous, L More by this author

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+ Hardacre, C More by this author

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+ Compton, R More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Physical & Theoretical Chem

Role:

Author

Bibliographic Details

Journal:: JOURNAL OF PHYSICAL CHEMISTRY C
Volume:: 112
Issue:: 16
Pages:: 6551-6557
Publication date:: 2008-04-24
DOI:: 10.1021/jp800145k
EISSN:: 1932-7455
ISSN:: 1932-7447

Item Description

Language:: English
UUID:: uuid:6f1b4776-3f0d-41d7-801f-fff8dfa6f10a
Local pid:: pubs:40726
Source identifiers:: 40726
Deposit date:: 2012-12-19

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Copyright date:: 2008

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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