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A rhodium-catalysed Sonogashira-type coupling exploiting C–S functionalisation: orthogonality with palladium-catalysed variants

Abstract:

This report concerns the development of an efficient Sonogashira-type coupling of arylmethylsulfides and terminal alkynes to generate aryl alkyne motifs. Orthogonal reactivity between traditional Pd catalysts, and the Rh catalysts employed, results in the ability to selectively activate either the C–S bond or C–X bond through catalyst choice. The Rh–bisphosphine catalyst has further been shown to be able to effect a hydroacylation-Sonogashira tandem sequence, and in combination with further o...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c9cc00092e

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
Lincoln College
Role:
Author
ORCID:
0000-0002-0636-6471
More from this funder
Name:
Engineering & Physical Sciences Research Council
Grant:
EP/K024205/1
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications More from this journal
Volume:
55
Pages:
2757-2760
Publication date:
2019-02-14
Acceptance date:
2019-01-25
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pubs id:
pubs:965919
UUID:
uuid:6f1a0d50-fdd1-4578-90b2-48c1383dba3e
Local pid:
pubs:965919
Source identifiers:
965919
Deposit date:
2019-01-25

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