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Photodissociation dynamics of OCS at 248 nm: the S((1)D(2)) atomic angular momentum polarization.

Abstract:

The dissociation of OCS has been investigated subsequent to excitation at 248 nm. Speed distributions, speed dependent translational anisotropy parameters, angular momentum alignment, and orientation are reported for the channel leading to S((1)D(2)). In agreement with previous experiments, two product speed regimes have been identified, correlating with differing degrees of rotational excitation in the CO coproducts. The velocity dependence of the translational anisotropy is also shown to be...

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Publication status:
Published

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Publisher copy:
10.1063/1.2757618

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Journal of chemical physics More from this journal
Volume:
127
Issue:
8
Pages:
084304
Publication date:
2007-08-01
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
Language:
English
Pubs id:
pubs:33953
UUID:
uuid:6f108683-5da5-4287-854e-df180fe2277e
Local pid:
pubs:33953
Source identifiers:
33953
Deposit date:
2012-12-19

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