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Total synthesis of polycephalin C and determination of the absolute configurations at the 3",4" ring junction.

Abstract:
Only through total synthesis could the absolute configuration of the 3′′R,4′′R ring junction of the polyenoltetramic acid polycephalin C (1) be unambiguously established. Key features of the synthesis include a double Swern oxidation, double Stille coupling, and a double Takai olefination.
Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Journal:
Angewandte Chemie (International ed. in English)
Volume:
41
Issue:
15
Pages:
2786-2790
Publication date:
2002-08-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:6eda0f35-4c6c-40e5-8b26-1ee6e113e15c
Source identifiers:
52084
Local pid:
pubs:52084

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