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REACTION-RATES OF IONS WITH DIPOLAR MOLECULES IN 2-PI ELECTRONIC STATES

Abstract:

Calculations of rate coefficients for the fast reaction of a structureless ion with a dipolar linear molecule in a 2Π electronic state are presented. The rotationally adiabatic capture theory is used together with a simple classical electrostatic potential. An analytical formula is derived for the rate coefficient in the low temperature limit. The reaction of H 3+ with OH(X2Π) is taken as an example. For temperatures less than 90 K, the rate coefficients differ from those calculated for molec...

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Publication status:
Published

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Publisher copy:
10.1063/1.462192
Journal:
JOURNAL OF CHEMICAL PHYSICS More from this journal
Volume:
96
Issue:
2
Pages:
1053-1061
Publication date:
1992-01-15
DOI:
ISSN:
0021-9606
Language:
English
Pubs id:
pubs:53027
UUID:
uuid:6ebad94f-b20a-4096-b875-2bb9748d65f9
Local pid:
pubs:53027
Source identifiers:
53027
Deposit date:
2013-11-17

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