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Ferromagnetic nitrides with the filled beta-Mn structure: Fe(2-x)M(x)Mo3N (M = Ni, Pd, Pt)

Abstract:

The introduction of group 10 metals into the hypothetical composition Fe2Mo3N allows the isolation of the solid solutions Fe2-xMxMo3N (M = Ni, Pd, Pt), which crystallize with the filled β-manganese structure (space group P4132, a ≈ 6.7 Å). These materials display ferromagnetism with the Curie temperature and saturation magnetization being dependent on the iron content; Fe1.25Mo0.75Mo3N shows the highest ordering temperature in each series (maximized at Tc = 225 K for M = Pt) and the highest m...

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Publication status:
Published

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Publisher copy:
10.1021/cm047859q

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
CHEMISTRY OF MATERIALS
Volume:
17
Issue:
7
Pages:
1867-1873
Publication date:
2005-04-05
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
Language:
English
Pubs id:
pubs:39455
UUID:
uuid:6e8b7bc1-e6cb-4390-a6b1-cb69b08fa0ea
Local pid:
pubs:39455
Source identifiers:
39455
Deposit date:
2012-12-19

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