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An experimental study of the dynamics of the reaction H+CO2 -> OH(v ',j ',f)+CO: Product state-resolved differential cross sections and translational energy release distributions

Abstract:

Angular distributions and pair-correlated translational energy distributions have been measured for OH(v′ = O, N′ = 1), produced through the reactive scattering of hot H atoms by CO2 at 300 K and mean collision energies of 1.8 eV and 2.5 eV. The new measurements, together with those reported previously for the OH(v′ = 0, N′ = 5, A′/A″) products of the reaction at 2.5 eV, reveal that the differential cross sections depend strongly on collision energy and product quantum state. For the OH(v′/ =...

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Publication status:
Published

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Publisher copy:
10.1021/jp982148z

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY A
Volume:
102
Issue:
47
Pages:
9559-9564
Publication date:
1998-11-19
DOI:
EISSN:
1520-5215
ISSN:
1089-5639
Source identifiers:
52535
Language:
English
Pubs id:
pubs:52535
UUID:
uuid:6e637f8e-74cf-45e8-a79e-f294aea121e7
Local pid:
pubs:52535
Deposit date:
2012-12-19

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