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[Rh(C7H8)(PPh3)Cl]: an experimental charge-density study.

Abstract:

In order to gain a deeper understanding into the bonding situation in rhodium complexes containing rhodium-carbon interactions, the experimental charge-density analysis for [Rh(C(7)H(8))(PPh(3))Cl] (1) is reported. Accurate, high-resolution (sin theta/lambda = 1.08 A(-1)), single-crystal data were obtained at 100 K. The results from the investigation were interesting in relation to the interactions between the rhodium metal centre and the norbornadiene fragment and illustrate the importance o...

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Publication status:
Published

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Publisher copy:
10.1107/s0108768108026384

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Acta crystallographica. Section B, Structural science
Volume:
64
Issue:
Pt 5
Pages:
550-557
Publication date:
2008-10-01
DOI:
EISSN:
1600-5740
ISSN:
0108-7681
Language:
English
Keywords:
Pubs id:
pubs:40930
UUID:
uuid:6e2a3cba-1c43-462c-9ff0-656e0abd0eef
Local pid:
pubs:40930
Source identifiers:
40930
Deposit date:
2012-12-19

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