- Abstract:
-
The cyclic voltammetry at electrodes composed of multiple electroactive materials, where zones of one highly active material are distributed over a substrate of a second, less active material, is investigated by simulation. The two materials are assumed to differ in terms of their electrochemical rate constants towards any given redox couple. For a one-electron oxidation or reduction, the effect on voltammetry of the size and relative surface coverages of the zones as well as the rate constan...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/c2cp40412e
-
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- Journal:
- Physical chemistry chemical physics : PCCP
- Volume:
- 14
- Issue:
- 20
- Pages:
- 7264-7275
- Publication date:
- 2012-05-05
- DOI:
- EISSN:
-
1463-9084
- ISSN:
-
1463-9076
- URN:
-
uuid:6e153b5e-ed19-407d-b574-e2f935b17726
- Source identifiers:
-
325205
- Local pid:
- pubs:325205
- Language:
- English
- Copyright date:
- 2012
Journal article
The theory of cyclic voltammetry of electrochemically heterogeneous surfaces: comparison of different models for surface geometry and applications to highly ordered pyrolytic graphite.
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