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Vibrational distribution in NO(X2Pi) formed by self quenching of NO A 2Sigma+ (v=0).

Abstract:

Time-resolved FTIR has been used to study the emission from the NO X 2Pi (v) products formed both by fluorescence and by collisional self quenching of the NO A 2Sigma+ (v=0) state. Vibrational excitation has been observed in ground state NO with populations up to at least v=20. Under conditions where fluorescence is the dominant removal process the nascent distribution in ground state NO(v) was found to be determined by the relative magnitude of the emission coefficients. Collisional quenchin...

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Publication status:
Published

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Publisher copy:
10.1039/b719065d

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
10
Issue:
15
Pages:
2014-2019
Publication date:
2008-04-01
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Source identifiers:
34345
Language:
English
Keywords:
Pubs id:
pubs:34345
UUID:
uuid:6e0a018e-560e-4cc4-9273-d039d807a79f
Local pid:
pubs:34345
Deposit date:
2012-12-19

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