Journal article
Asymmetric synthesis of 2-alkyl- and 2-aryl-3-aminopropionic acids (beta2-amino acids) from (S)-N-acryloyl-5,5-dimethyloxazolidin-2-one SuperQuat derivatives.
- Abstract:
- Conjugate addition of lithium amides to (S)-N-acryloyl- or (S)-N-2'-alkylacryloyloxazolidinones and alkylation or protonation of the resulting enolates with 2-pyridone respectively provides a highly stereoselective and product complementary route to a range of (R)- and (S)-2-alkyl-3-aminopropionic acids in good yield and in high ee.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/b410938d
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Authors
Bibliographic Details
- Journal:
- Chemical Communications
- Issue:
- 23
- Pages:
- 2778-2779
- Publication date:
- 2004-12-01
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- Source identifiers:
-
32921
Item Description
- Language:
- English
- Pubs id:
-
pubs:32921
- UUID:
-
uuid:6dee6231-d888-452e-afca-fc776642a077
- Local pid:
- pubs:32921
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2004
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