Journal article
Argentophilicity-dependent colossal thermal expansion in extended prussian blue analogues.
- Abstract:
-
The thermal expansion behavior of isostructural variants of the colossal thermal expansion material Ag3[CoIII(CN)6] has been investigated using variable temperature X-ray and neutron powder diffraction. It was found that substitution at the octahedral transition metal site did not strongly affect the thermal expansion behavior, giving Ag3[FeIII(CN)6] as a new colossal thermal expansion material. Substitution at the Ag site (by D) was shown to reduce the thermal expansion coefficients by an or...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- Journal of the American Chemical Society
- Volume:
- 130
- Issue:
- 30
- Pages:
- 9660-9661
- Publication date:
- 2008-07-01
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
Item Description
- Language:
- English
- Pubs id:
-
pubs:50525
- UUID:
-
uuid:6de98a08-20c2-4aae-8544-aa056d94ab51
- Local pid:
- pubs:50525
- Source identifiers:
-
50525
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2008
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