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Argentophilicity-dependent colossal thermal expansion in extended prussian blue analogues.

Abstract:

The thermal expansion behavior of isostructural variants of the colossal thermal expansion material Ag3[CoIII(CN)6] has been investigated using variable temperature X-ray and neutron powder diffraction. It was found that substitution at the octahedral transition metal site did not strongly affect the thermal expansion behavior, giving Ag3[FeIII(CN)6] as a new colossal thermal expansion material. Substitution at the Ag site (by D) was shown to reduce the thermal expansion coefficients by an or...

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Publication status:
Published

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Publisher copy:
10.1021/ja803623u

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Journal:
Journal of the American Chemical Society More from this journal
Volume:
130
Issue:
30
Pages:
9660-9661
Publication date:
2008-07-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:50525
UUID:
uuid:6de98a08-20c2-4aae-8544-aa056d94ab51
Local pid:
pubs:50525
Source identifiers:
50525
Deposit date:
2012-12-19

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