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Electrochemically initiated catalytic oxidation of 5-thio-2-nitrobenzoic acid (TNBA) in the presence of thiols at a boron doped diamond electrode: Implications for total thiol detection

Abstract:: The electrochemical response of 5,5-dithiobis(2-nitrobenzoic acid) (DTNB) to increasing additions of thiol species has been examined at a boron doped diamond electrode. A reaction has been shown to occur with a range of biologically relevant thiols and proceeds via a CECC' process. A total thiol detection methodology has been developed showing that the sensitivities of the standard addition plots are independent of the individual thiol species added to the solution. The analytical utility of ...
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Publication status:: Published

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APA Style

Nekrassova, O., Lawrence, N., & Compton, R. (2003). Electrochemically initiated catalytic oxidation of 5-thio-2-nitrobenzoic acid (TNBA) in the presence of thiols at a boron doped diamond electrode: Implications for total thiol detection. ELECTROANALYSIS, 15(21), 1655–1660.

MLA Style

Nekrassova, O., et al. “Electrochemically Initiated Catalytic Oxidation of 5-Thio-2-Nitrobenzoic Acid (TNBA) in the Presence of Thiols at a Boron Doped Diamond Electrode: Implications for Total Thiol Detection.” ELECTROANALYSIS, vol. 15, no. 21, 2003, pp. 1655–60.

Chicago Style

Nekrassova, O, N Lawrence, and R Compton. 2003. “Electrochemically Initiated Catalytic Oxidation of 5-Thio-2-Nitrobenzoic Acid (TNBA) in the Presence of Thiols at a Boron Doped Diamond Electrode: Implications for Total Thiol Detection.” ELECTROANALYSIS 15 (21): 1655–60.
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Publisher copy:: 10.1002/elan.200302799

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+ Nekrassova, O More by this author

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+ Lawrence, N More by this author

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+ Compton, R More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Physical & Theoretical Chem

Role:

Author

Bibliographic Details

Journal:: ELECTROANALYSIS
Volume:: 15
Issue:: 21
Pages:: 1655-1660
Publication date:: 2003-11-01
DOI:: 10.1002/elan.200302799
EISSN:: 1521-4109
ISSN:: 1040-0397

Item Description

Keywords:: thiols

CECC ' mechanism

5-thio-2-nitrobenzoic acid (TNBA)

boron doped diamond

post column detection
UUID:: uuid:6dac2164-d408-4572-a6ec-e9941908a5bf
Local pid:: pubs:38892
Source identifiers:: 38892
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2003

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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