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Calix[4]arene-based rotaxane host systems for anion recognition.

Abstract:

The synthesis, structure and anion binding properties of the first calix[4]arene-based [2]rotaxane anion host systems are described. Rotaxanes 9.Cl and 12.Cl, consisting of a calix[4]arene functionalised macrocycle wheel and different pyridinium axle components, are prepared via adaption of an anion templated synthetic strategy to investigate the effect of preorganisation of the interlocked host's binding cavity on anion binding. Rotaxane 12.Cl contains a conformationally flexible pyridinium ...

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Publication status:
Published

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Publisher copy:
10.1002/chem.200902659

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Volume:
16
Issue:
4
Pages:
1256-1264
Publication date:
2010-01-01
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Source identifiers:
34995
Language:
English
Keywords:
Pubs id:
pubs:34995
UUID:
uuid:6d9b4c9c-d32f-4192-b2af-3704d3278f41
Local pid:
pubs:34995
Deposit date:
2012-12-19

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