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Synthesis and structural chemistry of La18Li8Rh4MO39 (M=Ti, Mn, Ru)

Abstract:

Polycrystalline samples of La18Li8Rh4MO39 (M=Ti, Mn, Ru) have been prepared by a solid-state method and studied by neutron powder diffraction. They are isostructural with La18Li8Rh5O39 and adopt the cubic space group P m over(3, -) n with a ∼12.22 Å. Their structure consists of a La-O framework containing intersecting channels that run along 〈111〉. These channels are occupied by chains made up of alternating, face-sharing trigonal-prismatic and octahedral coordination polyhedra; there are two...

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Publication status:
Published

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Publisher copy:
10.1016/j.jssc.2010.05.005

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Dutton, SE More by this author
van Daesdonk, PA More by this author
Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
183
Issue:
7
Pages:
1620-1624
Publication date:
2010-07-05
DOI:
EISSN:
1095-726X
ISSN:
0022-4596
URN:
uuid:6d94cb8e-3b95-4753-a3b9-078a507ac92c
Source identifiers:
65961
Local pid:
pubs:65961

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