- Abstract:
-
Polycrystalline samples of La18Li8Rh4MO39 (M=Ti, Mn, Ru) have been prepared by a solid-state method and studied by neutron powder diffraction. They are isostructural with La18Li8Rh5O39 and adopt the cubic space group P m over(3, -) n with a ∼12.22 Å. Their structure consists of a La-O framework containing intersecting channels that run along 〈111〉. These channels are occupied by chains made up of alternating, face-sharing trigonal-prismatic and octahedral coordination polyhedra; there are two...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.jssc.2010.05.005
-
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- Journal:
- JOURNAL OF SOLID STATE CHEMISTRY
- Volume:
- 183
- Issue:
- 7
- Pages:
- 1620-1624
- Publication date:
- 2010-07-05
- DOI:
- EISSN:
-
1095-726X
- ISSN:
-
0022-4596
- URN:
-
uuid:6d94cb8e-3b95-4753-a3b9-078a507ac92c
- Source identifiers:
-
65961
- Local pid:
- pubs:65961
- Language:
- English
- Keywords:
- Copyright date:
- 2010
Journal article
Synthesis and structural chemistry of La18Li8Rh4MO39 (M=Ti, Mn, Ru)
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