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Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.

Abstract:
The pathway for the combination of enones and beta-S-substituted aldehydes using Rh-catalysis can be switched between a hydroacylation reaction or a reductive aldol reaction by simple choice of the phosphine ligand; this catalyst controlled switch allows access to new ketone hydroacylation products; useful 1,4-diketone intermediates for the synthesis of N-, S- and O-heterocycles.
Publication status:
Published

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Publisher copy:
10.1039/b810935d

Authors


Osborne, JD More by this author
Willis, MC More by this author
Journal:
Chemical communications (Cambridge, England)
Issue:
40
Pages:
5025-5027
Publication date:
2008-10-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:6d7722c9-6ac0-4f43-a6ba-ca66c783678d
Source identifiers:
52477
Local pid:
pubs:52477
Language:
English

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