Journal article
Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.
- Abstract:
- The pathway for the combination of enones and beta-S-substituted aldehydes using Rh-catalysis can be switched between a hydroacylation reaction or a reductive aldol reaction by simple choice of the phosphine ligand; this catalyst controlled switch allows access to new ketone hydroacylation products; useful 1,4-diketone intermediates for the synthesis of N-, S- and O-heterocycles.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/b810935d
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Authors
Bibliographic Details
- Journal:
- Chemical Communications
- Issue:
- 40
- Pages:
- 5025-5027
- Publication date:
- 2008-10-01
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- Source identifiers:
-
52477
Item Description
- Language:
- English
- Pubs id:
-
pubs:52477
- UUID:
-
uuid:6d7722c9-6ac0-4f43-a6ba-ca66c783678d
- Local pid:
- pubs:52477
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2008
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