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Silver-phosphine complexes of the highly methylated carborane monoanion [closo-1-H-CB11Me11]-.

Abstract:

The synthesis of the silver(I) salt of the highly methylated carborane anion [closo-1-H-CB(11)Me(11)](-) is described, Ag[closo-1-H-CB(11)Me(11)] 1, which in the solid state shows close intermolecular Ag...H(3)C contacts. Addition of various monodentate phosphines to 1 results in the formation of the complexes (R(3)P)Ag[closo-1-H-CB(11)Me(11)] [R = Ph, 2; cyclohexyl (C(6)H(11)), 3; (3,5-Me(2)-C(6)H(3)), 4]. All these complexes show close intermolecular Ag.H(3)C contacts in the solid state tha...

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Publication status:
Published

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Publisher copy:
10.1021/ja038173m

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Journal:
Journal of the American Chemical Society More from this journal
Volume:
126
Issue:
5
Pages:
1503-1517
Publication date:
2004-02-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:51686
UUID:
uuid:6d632c87-1882-41c8-957f-d84fea79b462
Local pid:
pubs:51686
Source identifiers:
51686
Deposit date:
2012-12-19

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