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Dynamics of inelastic scattering of OH radicals from reactive and inert liquid surfaces

Abstract:

The inelastic scattering of gas-phase OH radicals from a liquid hydrocarbon and a liquid perfluorinated polyether (PFPE) has been investigated. The surfaces examined were the potentially reactive, branched hydrocarbon squalane (CH, 2,6,10,15,19,23-hexamethyltetracosane) and the inert PFPE Krytox 1506 (F-[CF(CF)-CFO] -CFCF). Superthermal OH was formed by 355-nm laser photolysis of a low pressure of HONO above the liquid surface. Laser-induced fluorescence (LIF) was used to determine the relati...

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Publisher copy:
10.1021/jp8024683

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Institution:
University of Oxford
Department:
Oxford, MPLS, Materials
Role:
Author
Journal:
Journal of Physical Chemistry C
Volume:
112
Issue:
29
Pages:
10868-10877
Publication date:
2008-07-24
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:6d615b7d-66d8-4ec9-98a6-23767aa8853e
Source identifiers:
291875
Local pid:
pubs:291875

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