Journal article icon

Journal article

Electrochemical oxidation of nitrite and the oxidation and reduction of NO2 in the room temperature ionic liquid [C2mim][NTf2].

Abstract:

The electrochemical oxidation of potassium nitrite has been studied in the room temperature ionic liquid (RTIL) [C2mim][NTf2] by cyclic voltammetry at platinum electrodes. A chemically irreversible oxidation peak was observed, and a solubility of 7.5(+/-0.5) mM and diffusion coefficient of 2.0(+/-0.2)x10(-11) m2 s(-1) were calculated from potential step chronoamperometry on the microdisk electrode. A second, and sometimes third, oxidation peak was also observed when the anodic limit was exten...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/jp0728104

Authors


Broder, TL More by this author
Silvester, DS More by this author
Hardacre, C More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
The journal of physical chemistry. B
Volume:
111
Issue:
27
Pages:
7778-7785
Publication date:
2007-07-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:6d5599d0-0b59-458b-800d-7bbdd96bb6a9
Source identifiers:
33886
Local pid:
pubs:33886

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP