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Comparative solubilisation of potassium carbonate, sodium bicarbonate and sodium carbonate in hot dimethylformamide: application of cylindrical particle surface-controlled dissolution theory.

Abstract:

A surface-controlled dissolution of cylindrical solid particles model is applied to potassium carbonate, sodium bicarbonate and sodium carbonate in dimethylformamide at elevated temperatures. Previously published data for the dissolution of potassium carbonate is interpreted assuming a cylindrical rather than a spherical shape of the particles, the former representing a closer approximation to the true shape of the particles as revealed by scanning electron microscopy. The dissolution kinetic...

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Publication status:
Published

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Publisher copy:
10.1039/b512463h

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
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Journal:
Physical chemistry chemical physics : PCCP
Volume:
8
Issue:
5
Pages:
633-641
Publication date:
2006-02-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:6d33d523-c709-4454-af6c-c730cb1df78a
Source identifiers:
33393
Local pid:
pubs:33393

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