Journal article
Bis(pentalene)dititanium chemistry: C–H, C–X and H–H bond activation
- Abstract:
-
The reaction of the bis(pentalene)dititanium complex Ti2(μ:η5,η5-Pn†)2 (Pn† = C8H4(1,4-SiiPr3)2) (1) with the N-heterocyclic carbene 1,3,4,5-tetramethylimidazol-2-ylidene results in intramolecular C–H activation of an isopropyl substituent to form a tucked-in hydride (3). Whilst pyridine will also effect this cyclometallation reaction to form (5), the pyridine analogue of (3), the bases 1,2,4,5-tetramethyl-imidazole, 2,6-lutidine, DABCO or trimethylphosphine are ineffective. The reaction of (...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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Funding
Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Dalton Transactions Journal website
- Volume:
- 41
- Pages:
- 14531–14539
- Publication date:
- 2018-09-17
- Acceptance date:
- 2018-09-17
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- Pmid:
-
30252008
Item Description
- Language:
- English
- Pubs id:
-
pubs:923815
- UUID:
-
uuid:6d22dff5-d1c1-4b5f-ba58-e65629fc8b24
- Local pid:
- pubs:923815
- Source identifiers:
-
923815
- Deposit date:
- 2018-10-14
Terms of use
- Copyright holder:
- Royal Society of Chemistry
- Copyright date:
- 2018
- Notes:
- © The Royal Society of Chemistry 2018. This is the accepted manuscript version of the article. The final version is available online from Royal Society of Chemistry at: https://doi.org/10.1039/c8dt02654h
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