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Catalytic mechanism in cyclic voltammetry at disc electrodes: an analytical solution.

Abstract:

The theory of cyclic voltammetry at disc electrodes and microelectrodes is developed for a system where the electroactive reactant is regenerated in solution using a catalyst. This catalytic process is of wide importance, not least in chemical sensing, and it can be characterized by the resulting peak current which is always larger than that of a simple electrochemical reaction; in contrast the reverse peak is always relatively diminished in size. From the theoretical point of view, the probl...

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Publication status:
Published

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Publisher copy:
10.1039/c1cp21181a

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
13
Issue:
32
Pages:
14694-14704
Publication date:
2011-08-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:6d054755-5a6a-48f1-a78c-a756cd242277
Source identifiers:
166492
Local pid:
pubs:166492
Language:
English

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