- Abstract:
-
The theory of cyclic voltammetry at disc electrodes and microelectrodes is developed for a system where the electroactive reactant is regenerated in solution using a catalyst. This catalytic process is of wide importance, not least in chemical sensing, and it can be characterized by the resulting peak current which is always larger than that of a simple electrochemical reaction; in contrast the reverse peak is always relatively diminished in size. From the theoretical point of view, the probl...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/c1cp21181a
-
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- Journal:
- Physical chemistry chemical physics : PCCP
- Volume:
- 13
- Issue:
- 32
- Pages:
- 14694-14704
- Publication date:
- 2011-08-05
- DOI:
- EISSN:
-
1463-9084
- ISSN:
-
1463-9076
- URN:
-
uuid:6d054755-5a6a-48f1-a78c-a756cd242277
- Source identifiers:
-
166492
- Local pid:
- pubs:166492
- Language:
- English
- Copyright date:
- 2011
Journal article
Catalytic mechanism in cyclic voltammetry at disc electrodes: an analytical solution.
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