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[Microwave activation of electrochemical processes: convection, thermal gradients and hot spot formation at the electrode | solution interface

Abstract:

Microwave activation of electrochemical processes is possible by self-focussing of intense microwave radiation at the electrode I solution (electrolyte) interface of an electrode immersed in a solution and placed in a microwave cavity. Considerable changes in voltammetric current responses are observed experimentally for the one-electron reduction of Ru(NH3)63+ in aqueous 0.1 M KCl and for the stepwise two-electron reduction of the methylviologen dication (MV2+) in aqueous 0.1 M NaCl. The for...

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Publication status:
Published

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Publisher copy:
10.1039/b003413o

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
NEW JOURNAL OF CHEMISTRY
Volume:
24
Issue:
9
Pages:
653-658
Publication date:
2000-01-01
DOI:
EISSN:
1369-9261
ISSN:
1144-0546
URN:
uuid:6ce72de8-980d-4cee-aeb6-b309ca49f9fc
Source identifiers:
37612
Local pid:
pubs:37612
Language:
English

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