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Hypervalent iodine initiated intramolecular alkene dimerisation: a stereodivergent entry to cyclobutanes

Abstract:

The emergence of new methods for the stereoselective synthesis of strained carbocycles is a challenging but worthwhile endeavour. Cyclobutanes, in particular, have attracted the attention of both medicinal chemists and material scientists for their unique properties. Herein, we present a new method that allows access to highly functionalized cyclobutanes with complementary all-trans and trans–cis–trans relative stereochemistry, that could not be accessed befor...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/C9CC04383G

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
Magdalen College
Role:
Author
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Name:
European Commission
Grant:
626501
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications More from this journal
Volume:
55
Issue:
69
Pages:
10316-10319
Publication date:
2019-08-12
Acceptance date:
2019-08-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Keywords:
Pubs id:
pubs:1038566
UUID:
uuid:6cbce051-825d-46a1-967e-7acc919b0fd4
Local pid:
pubs:1038566
Source identifiers:
1038566
Deposit date:
2019-08-05

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