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Direct measurements of ionic liquid layering at a single mica-liquid interface and in nano-films between two mica-liquid interfaces.

Abstract:

The layering of ionic liquids close to flat, charged interfaces has been identified previously through theoretical and some experimental measurements. Here we present evidence for oscillations in ion density (‘layering’) in a long chain ionic liquid (1-decyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide) near the interface with mica using two complementary approaches. Neutron reflection at the ionic liquid-mica interface is used to detect structure at a single interface, and surface ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c6cp05757h

Authors


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Institution:
University of Oxford
Oxford college:
Trinity College
Role:
Author
John Fell Fund More from this funder
Engineering and Physical Sciences Research Council More from this funder
British Petroleum More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Physical Chemistry Chemical Physics Journal website
Volume:
19
Pages:
297-304
Publication date:
2016-11-01
Acceptance date:
2016-11-14
DOI:
ISSN:
1463-9084
Language:
English
Keywords:
Pubs id:
pubs:664030
UUID:
uuid:6c978adb-c58f-4dbb-83f8-8a12a4652f8f
Local pid:
pubs:664030
Source identifiers:
664030
Deposit date:
2016-12-29

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