The spectroscopy and UV photodissociation dynamics of Cu2 and CuO have been studied using a combination of one- and two-colour excitation and velocity map imaging. Resonant excitation of Cu2 via the J ← X (1)Σg(+) transition leads to significant fragmentation which is interpreted in terms of a combination of direct dissociation of Cu2(+ 2)Π produced in the resonant two-photon ionization process and dissociation of excited Cu2 states above the ionization threshold. By fitting of the kinetic en...Expand abstract
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Imaging the photodissociation dynamics of neutral metal clusters: copper dimer, Cu2, and copper oxide, CuO.
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