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Electrochemically induced intermolecular anion transfer.

Abstract:

Two macrocyclic anion receptors with the proper signaling units were designed to control intermolecular anion transfer using an electrochemical stimulus. The solubility of both receptors drastically improved when one equivalent of benzoate was added to the suspension in the NMR tube. Macrocycles 1 and 2 were prepared via multistep synthetic pathways. An important enhancement of the MLCT emission intensity was initially seen when benzoate was added to a solution of macrocycles 1. Spectroelectr...

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Publication status:
Published

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Publisher copy:
10.1002/chem.200900878

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany) More from this journal
Volume:
15
Issue:
31
Pages:
7534-7538
Publication date:
2009-08-01
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Language:
English
Keywords:
Pubs id:
pubs:41367
UUID:
uuid:6c7ec239-eb40-493a-97e7-74edf16121cb
Local pid:
pubs:41367
Source identifiers:
41367
Deposit date:
2012-12-19

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