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Cationic terminal gallylene complexes by halide abstraction: coordination chemistry of a valence isoelectronic analogue of CO and N2.

Abstract:

While N(2) and CO have played central roles in developing models of electronic structure, and their interactions with transition metals have been widely investigated, the valence isoelectronic diatomic molecules EX (E = group 13 element, X = group 17 element) have yet to be isolated under ambient conditions, either as the "free" molecule or as a ligand in a simple metal complex. As part of a program designed to address this deficiency, together with wider issues of the chemistry of cationic s...

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Publication status:
Published

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Publisher copy:
10.1021/ja806655f

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Journal of the American Chemical Society More from this journal
Volume:
130
Issue:
47
Pages:
16111-16124
Publication date:
2008-11-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:34464
UUID:
uuid:6c7a390c-8c31-49c3-a366-b4123edcdb00
Local pid:
pubs:34464
Source identifiers:
34464
Deposit date:
2012-12-19

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