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Synthesis and near-IR luminescence properties of neodymium(III) and ytterbium(III) complexes with poly(pyrazolyl) borate ligands

Abstract:

We have prepared neodymium(III) and ytterbium(III) complexes from a range of poly(pyrazolyl)borate ligands and studied their near-IR luminescence properties, in particular using solution lifetimes obtained in protonated and deuterated methanol to determine the extent of solvation of the complexes. For the neodymium complexes, the luminescence lifetime in methanolic solutions increases as solvent is excluded from the inner coordination sphere. However, for a given inner sphere coordination num...

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Publication status:
Published

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Publisher copy:
10.1039/b200519k

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS More from this journal
Issue:
9
Pages:
1923-1928
Publication date:
2002-01-01
DOI:
EISSN:
1364-5447
ISSN:
1472-7773
Language:
English
Pubs id:
pubs:38227
UUID:
uuid:6c5939e4-d09c-4143-b820-2e8820f77c08
Local pid:
pubs:38227
Source identifiers:
38227
Deposit date:
2012-12-19

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