Journal article icon

Journal article

Molecular orbital analysis of the trend in B-11 NMR chemical shifts for (Cp*M)(2)B5H9 (M = Cr, Mo, W; Cp* = eta(5)-C5Me5)

Abstract:

The 11B NMR shifts of the two types of boron atoms directly bonded to the metal atoms in (Cp*M)2B5H9 (M = Cr, Mo, W) experience a large systematic shift to higher field in going from Cr to Mo to W, whereas the shifts for the boron atoms connected to the metal atoms via M-H-B bridge bonds are invariant. The origin of this behavior is traced to two high-lying filled MO's and two low-lying unfilled MO's, both of which have metal and boron character. The energy differences of these sets of MO's c...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/om980808g

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS More from this journal
Volume:
18
Issue:
3
Pages:
447-450
Publication date:
1999-02-01
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Language:
English
Pubs id:
pubs:51723
UUID:
uuid:6c4a5644-186f-4306-8abc-f9e9dec65612
Local pid:
pubs:51723
Source identifiers:
51723
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP