- Abstract:
-
The photochemical reaction of Ru(CO)(3)(L)(2), where L = PPh(3), PMe(3), PCy(3) and P(p-tolyl)(3) with parahydrogen (p-H(2)) has been studied by in-situ NMR spectroscopy and shown to result in two competing processes. The first of these involves loss of CO and results in the formation of the cis-cis-trans-L isomer of Ru(CO)(2)(L)(2)(H)(2), while in the second, a single photon induces loss of both CO and L and leads to the formation of cis-cis-cis Ru(CO)(2)(L)(2)(H)(2) and Ru(CO)(2)(L)(solvent...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/b410912k
-
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- Journal:
- Dalton transactions (Cambridge, England : 2003)
- Issue:
- 21
- Pages:
- 3616-3628
- Publication date:
- 2004-11-05
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- URN:
-
uuid:6c1b601a-6e7e-4782-b278-02550bd87b90
- Source identifiers:
-
645
- Local pid:
- pubs:645
- Language:
- English
- Copyright date:
- 2004
Journal article
A combined parahydrogen and theoretical study of H2 activation by 16-electron d8 ruthenium(0) complexes and their subsequent catalytic behaviour.
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