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A combined parahydrogen and theoretical study of H2 activation by 16-electron d8 ruthenium(0) complexes and their subsequent catalytic behaviour.

Abstract:

The photochemical reaction of Ru(CO)(3)(L)(2), where L = PPh(3), PMe(3), PCy(3) and P(p-tolyl)(3) with parahydrogen (p-H(2)) has been studied by in-situ NMR spectroscopy and shown to result in two competing processes. The first of these involves loss of CO and results in the formation of the cis-cis-trans-L isomer of Ru(CO)(2)(L)(2)(H)(2), while in the second, a single photon induces loss of both CO and L and leads to the formation of cis-cis-cis Ru(CO)(2)(L)(2)(H)(2) and Ru(CO)(2)(L)(solvent...

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Publication status:
Published

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Publisher copy:
10.1039/b410912k

Authors


Blazina, D More by this author
Carteret, HA More by this author
Duckett, SB More by this author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
21
Pages:
3616-3628
Publication date:
2004-11-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:6c1b601a-6e7e-4782-b278-02550bd87b90
Source identifiers:
645
Local pid:
pubs:645
Language:
English

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