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HOMOGENEOUS CATALYSIS OF ELECTROCHEMICAL REACTIONS - MECHANISTIC RESOLUTION VIA ROTATING-DISK ELECTRODE VOLTAMMETRIC WAVESHAPE ANALYSIS

Abstract:
The shape of the current-voltage curves at a rotating disc electrode have been calculated for various nuances of the catalytic (EC') mechanism. In particular the halfwave potential is found to be highly sensitive to the disc rotation speed and the concentrations of mediator and substrate employed. These observations provide a ready method of characterising the different pathways. © 1989.
Publication status:
Published

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Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
264
Issue:
1-2
Pages:
1-25
Publication date:
1989-06-09
DOI:
ISSN:
1572-6657
Source identifiers:
43066
Language:
English
UUID:
uuid:6bcceb77-cd95-469b-972c-f3e6ec6db39a
Local pid:
pubs:43066
Deposit date:
2012-12-19

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