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Voltammetric study of the reaction of the 2-cyanophenoxide anion with carbon dioxide in dimethylformamide

Abstract:

The electrochemical reduction of 2-cyanophenol was studied in dimethylformamide (DMF) at a platinum microdisk electrode in the absence of carbon dioxide and with saturations of 10% and 100% carbon dioxide. Upon introduction of carbon dioxide it was inferred that the 2-cyanophenoxide anion, formed after the reduction of 2-cyanophenol and concomitant rapid protonation of the radical anion, reacts with carbon dioxide to form a possible cyanophenoxide-carbon dioxide complex. The latter then under...

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Publication status:
Published

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Publisher copy:
10.1039/b403966c

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
PHYSICAL CHEMISTRY CHEMICAL PHYSICS More from this journal
Volume:
6
Issue:
11
Pages:
2989-2993
Publication date:
2004-06-07
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Language:
English
UUID:
uuid:6b89297d-4a68-4e64-9df8-00cdd9dfe0b9
Local pid:
pubs:39073
Source identifiers:
39073
Deposit date:
2012-12-19

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