Journal article icon

Journal article

Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics

Abstract:
The theory of "two-dimensional voltammetry" using arrays of gold channel microband electrodes ranging in size from the millimeter to the micrometer scale is extended to permit the deduction of electrochemical rate constants through the analysis of hydrodynamic voltammograms as a function of both electrode size and electrolyte flow rate (convection). The technique is applied to the reduction of p-chloranil and the oxidation of 2,3,7,8-tetramethoxythianthrene both in acetonitrile solution and electrochemical rate constants are reported.
Publication status:
Published

Actions


Access Document


Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Expand authors...
Journal:
ELECTROANALYSIS
Volume:
11
Issue:
8
Pages:
541-545
Publication date:
1999-06-05
DOI:
ISSN:
1040-0397
URN:
uuid:6b825d69-9093-4d72-be07-d8c7983b5618
Source identifiers:
37056
Local pid:
pubs:37056

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP