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Tetrakis(dimethylamido)vanadium(IV).

Abstract:
The title compound, [V(C(2)H(6)N)(4)], (I), has non-crystallographic D(2d) molecular symmetry and contains an approximately tetrahedrally coordinated V atom with dimethylamido ligands. Each N atom features a nearly trigonal planar geometry. There are two independent molecules of (I) in the asymmetric unit. The results are compared with those previously reported for gas-phase electron-diffraction studies [Haaland, Rypdal, Volden and Andersen (1992). J. Chem. Soc. Dalton Trans. pp. 891-895].
Publication status:
Published

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Publisher copy:
10.1107/s0108270101008368

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Acta crystallographica. Section C, Crystal structure communications
Volume:
57
Issue:
Pt 8
Pages:
902-904
Publication date:
2001-08-01
DOI:
EISSN:
1600-5759
ISSN:
0108-2701
Source identifiers:
51025
Language:
English
Pubs id:
pubs:51025
UUID:
uuid:6b5dbec7-b339-42f0-ba50-0a816dff3b19
Local pid:
pubs:51025
Deposit date:
2012-12-19

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